Knudsen
cell measurements can be used to determine reaction probabilities
of gases on solid surfaces under dry condtions. These kinetic
measurements are needed in order to quantify heterogeneous
atmospheric processes for input in global atmospheric models.
The flow of gas through a cell at low pressures is measured
in the presence and absence of a reactive surface, in our
experiments we are interested in the uptake of gases on
components of mineral dust aerosol. The particles (e.g.
CaCO3, alpha-Fe2O3, kaolinite…)
are placed inside of a sample holder. A plunger with a
cover at end is used to isolate the metal oxide particles
from the gas. The flow of gas through the cell is monitored
with a UTI-Detector II quadrupole mass spectrometer (QMS).
Initially, the cover is in place so that the reactive particles
are not exposed. After a steady-state flow is established
through the low pressure cell, the cover is lifted up to
expose the metal oxide particles. The design of the Knudsen
cell is such that the volume of the cell stays constant
when the metal oxide particles are exposed. Therefore,
no volume corrections need to be made and the reaction
probability, gamma. A diagram of our multi-sample holder
Knudsen cell reactor is shown below.
